Asymptotic Analysis


The rate-ratio asymptotic analysis has been applied to predict the flame structure and extinction diameter for methanol burning in air. The flame structure is shown in the following figure, in which Z is the mixture fraction, with Z = 0 in the atmasphere and Z = 1 in the fuel.

The fuel-consumption zone is located at Z0. In this layer, reaction I occurs where CH3OH molecules are attacked by H atoms to form CO and H2. On the lean side of the fuel-consumption layer exists a H2 and CO oxidation layer, where H2 and CO are oxidized to form CO2 and H2O.


The predicted extinction diameters of pure methanol droplets, burning in oxygen-nitrogen mixtures at 300 K, as function of the ambient oxygen mole fraction, for three different pressures, is shown in the following figure; solid curves are for two-step chemistry and points for three-step chemistry.

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