let allowed atoms be  N, AR, H, O, C, HE.
let additional species be N2,AR,HE.
let temperature exponent be n_k.
let order of reaction be n.
let units for A be [ cm^(3(n-1)) / ( s * mole^(n-1) * K^n_k ) ].
let units for E be [ kJ / mole ].

#P HYDROGEN-OXYGEN CHAIN

#PRef: rightley:1997:co
1f: 	H + O2 -> OH + O	 { a = 3.520E+16 n = -0.700 E =  71.420 } 
2f: 	H2 + O -> OH + H	 { a = 5.060E+04 n = 2.670 E =  26.320 } 
3f: 	H2 + OH -> H2O + H	 { a = 1.170E+09 n = 1.300 E =  15.210 }
#PRef: sanchez:2013:williams
4f: 	H2O + O -> 2OH	         { a = 7.00E+05 n = 2.33 E =  60.87 } 

#P DIRECT RECOMBINATION

#PRef: saxena:2005:williams
5f: 	H + H + M1 -> H2 + M1	{ a = 1.300E+18 n = -1.000 E =   0.000 } 
6f: 	H + OH + M2 -> H2O + M2	{ a = 4.000E+22 n = -2.000 E =   0.000 } 
7f: 	O + O + M3 -> O2 + M3	{ a = 6.170E+15 n = -0.500 E =   0.000 } 
8f: 	H + O + M4 -> OH + M4	{ a = 4.710E+18 n = -1.000 E =   0.000 } 
9f: 	O + OH + M4 -> HO2 + M4	{ a = 8.00E+15 n = 0.000 E =   0.000 } 

#P HYDROPEROXYL REACTIONS

#PRef: troe:2000:modeling, saxena:2005:williams
10f: 	H + O2 + M5 -> HO2 + M5	{ ai = 4.650E+12 ni = 0.440 Ei =   0.000 
			 a = 5.750E+19 n = -1.400 E =   0.000 
	fca = 5.000E-01 fcta = 1.000E-30 fcb = 5.000E-01 fctb = 1.000E+30
} 
#PRef: mueller:1999:flow
11f: 	HO2 + H -> 2OH	{ a = 7.080E+13 n = 0.000 E =   1.234 } 
12f: 	HO2 + H -> H2 + O2	{ a = 1.660E+13 n = 0.000 E =   3.443 } 
#PRef: rightley:1997:co
13f: 	HO2 + H -> H2O + O	{ a = 3.100E+13 n = 0.000 E =   7.200 } 
#PRef: warnatz:1984:cc
14f: 	HO2 + O -> OH + O2	{ a = 2.000E+13 n = 0.000 E =   0.000 } 
#PRef: hong:2013:symp
15.1f: 	HO2 + OH -> H2O + O2 	{ a = 7.000E+12 n = 0.000 E =  -4.580 } 
15.2f:  HO2 + OH -> H2O + O2    { a = 4.500E+14 n = 0.000 E =  45.730 }

#P HYDROGEN PEROXIDE REACTIONS

#PRef: sanchez:2013:williams
#P Change due to new OH thermodata
16f: 	2OH + M6 -> H2O2 + M6	{ ai = 9.550E+13 ni = -0.270 Ei =   0.000 
			 a = 2.760E+25 n = -3.200 E =  0.000  

	fca = 4.300E-01 fcta = 1.000E+30 fcb = 5.700E-01 fctb =  1.000E-30
} 
#PRef: sanchez:2013:williams
17.1f: 	2HO2 -> H2O2 + O2 	{a = 1.030E+14 n = 0.000 E = 46.20 }
17.2f:  2HO2 -> H2O2 + O2       {a = 1.940E+11 n = 0.000 E = -5.895 }
#PRef: saxena:2011:joint
18f: 	H2O2 + H -> HO2 + H2	{ a = 2.300E+13 n = 0.000 E =  33.263 }
#PRef: yetter:1991:cst
19f: 	H2O2 + H -> H2O + OH	{ a = 1.000E+13 n = 0.000 E =  15.000 } 
#PRef: sanchez:2013:williams
20.1f: 	H2O2 + OH -> H2O + HO2 	{a = 1.740E+12 n = 0.000 E =  1.330 }
20.2f:  H2O2 + OH -> H2O + HO2  {a = 7.590E+13 n = 0.000 E =  30.43 }                               
#PRef: rightley:1997:co
21f: 	H2O2 + O -> HO2 + OH	{ a = 9.630E+06 n = 2.000 E =  16.700 } 

#P CONVERSION OF CO TO CO2

#PRef: saxena:2011:joint
a21f: CO + O + M11 -> CO2 + M11     { ai = 1.800E+11 ni = 0.000 Ei =   9.975
                            a = 1.550E+24 n = -2.790 E = 17.535
 fcc = 1.0 fctc = 0.0 
}

#PRef: rightley:1997:co
22f: 	CO + OH -> CO2 + H	{ a = 4.400E+06 n = 1.500 E =  -3.100 } 
#PRef: saxena:2011:joint
23f: 	CO + HO2 -> CO2 + OH	{ a = 2.00E+13  n = 0.000 E =  96.000 } 
#PRef: saxena:2005:williams
24f: 	CO + O2 -> CO2 + O	{ a = 1.000E+12 n = 0.000 E = 199.577 } 

#P FORMYL (HCO) REACTIONS

#PRef: lindstedt:1997:acetylene
25f: 	HCO + M7 -> CO + H + M7	{ a = 1.860E+17 n = -1.000 E =  71.130 }
#PRef: saxena:2007:thesis
26f: 	HCO + H -> CO + H2	{ a = 5.000E+13 n = 0.000 E =   0.000 }
#PRef: rightley:1997:co
27f: 	HCO + O -> CO + OH	{ a = 3.000E+13 n = 0.000 E =   0.000 } 
28f: 	HCO + O -> CO2 + H	{ a = 3.000E+13 n = 0.000 E =   0.000 } 
#PRef: tsang:1986
29f: 	HCO + OH -> CO + H2O	{ a = 3.000E+13 n = 0.000 E =   0.000 } 
#PRef:  saxena:2007:thesis
30f: 	HCO + O2 -> CO + HO2	{ a = 7.580E+12 n = 0.000 E =   1.715 } 
#PRef:  saxena:2007:thesis
31f: 	HCO + CH3 -> CO + CH4	{ a = 5.000E+13 n = 0.000 E =   0.000 } 

#P FORMALDEHYDE (CH2O) REACTIONS

#PRef: webpage:gri12
32f: 	H + HCO + M8 -> CH2O + M8	{ ai = 1.090E+12 ni = 0.480 Ei =  -1.088 
			 a = 1.350E+24 n = -2.570 E =   1.778 

	fca = 2.176E-01 fcta = 2.710E+02 fcb = 7.824E-01 fctb = 2.755E+03 fcc = 1 fctc = 6.570E+03 
} 
#PRef: li:thesis
33f: 	CH2O + H -> HCO + H2	{ a = 5.740E+07 n = 1.900 E =  11.500 } 
#PRef: rightley:1997:co
34f: 	CH2O + O -> HCO + OH	{ a = 3.500E+13 n = 0.000 E =  14.700 } 
35f: 	CH2O + OH -> HCO + H2O	{ a = 3.900E+10 n = 0.890 E =   1.700 } 
#PRef: baulch:1992:physchem
36f: 	CH2O + O2 -> HCO + HO2	{ a = 6.000E+13 n = 0.000 E = 170.180 } 
#PRef: eiteneer:1998
37f: 	CH2O + HO2 -> HCO + H2O2	{ a = 4.110E+04 n = 2.500 E =  42.720 } 

#P METHANE (CH4) Consumption

#PRef: hewson:1999:methane
38f: 	CH4 + H -> H2 + CH3	{ a = 1.300E+04 n = 3.000 E =  33.630 } 
39f: 	CH4 + OH -> H2O + CH3	{ a = 1.600E+07 n = 1.830 E =  11.640 } 
#PRef: frenklach:1992:pecs
40f: 	CH4 + O -> CH3 + OH	{ a = 1.900E+09 n = 1.440 E =  36.300 }
#PRef: lindstedt:1997:acetylene, li:2000:methaneign
41f: 	CH4 + O2 -> CH3 + HO2	{ a = 3.980E+13 n = 0.000 E = 238.030 } 
42f: 	CH4 + HO2 -> CH3 + H2O2	{ a = 9.030E+12 n = 0.000 E = 103.100 } 

#P METHYL (CH3) Reactions

#PRef: frenklach:1992:pecs
43f: 	CH3 + H -> T-CH2 + H2	{ a = 1.800E+14 n = 0.000 E =  63.200 } 
44f: 	CH3 + H -> S-CH2 + H2	{ a = 1.550E+14 n = 0.000 E =  56.400 } 
#PRef: grotheer:1992, saxena:2007:thesis
45f: 	CH3 + OH -> S-CH2 + H2O	{ a = 4.000E+13 n = 0.000 E =  10.470 } 
#PRef: frenklach:1992:pecs
46f: 	CH3 + O -> CH2O + H	{ a = 8.430E+13 n = 0.000 E =   0.000 }
#PRef: baulch:1992:physchem
47f: 	CH3 + T-CH2 -> C2H4 + H	{ a = 4.220E+13 n = 0.000 E =   0.000 }
#PRef: frenklach:1992:pecs
#P modification: preexponential 'a' has been changed to improve ignition-time calculations
48f: 	CH3 + HO2 -> CH3O + OH	{ a = 5.000E+12 n = 0.000 E =   0.000 } 
#PRef: zellner:1988
49f: 	CH3 + O2 -> CH2O + OH	{ a = 3.300E+11 n = 0.000 E =  37.410 } 
50f: 	CH3 + O2 -> CH3O + O	{ a = 1.100E+13 n = 0.000 E = 116.399 } 
#PRef: hidaka:1990:intjchemkin
51f: 	CH3 + CH3 -> C2H4 + H2	{ a = 1.000E+14 n = 0.000 E = 133.900 } 
#PRef: lim:1994:25th
52f: 	CH3 + CH3 -> C2H5 + H	{ a = 3.160E+13 n = 0.000 E =  61.500 } 

#PRef: saxena:2007:thesis
53f: 	H + CH3 + M9 -> CH4 + M9	{ ai = 1.270E+16 ni = -0.630 Ei =   1.602 
			 a = 2.470E+33 n = -4.760 E =  10.209 

	fca = 2.170E-01 fcta = 7.400E+01 fcb = 7.830E-01 fctb = 2.941E+03 fcc = 1 fctc = 6.964E+03 
} 
#PRef: hewson:1999:methane
54f: 	2CH3 + M8 -> C2H6 + M8	{ ai = 1.810E+13 ni = 0.000 Ei =   0.000 
			 a = 1.270E+41 n = -7.000 E =  11.560 

	fca = 3.800E-01 fcta = 7.300E+01 fcb = 6.200E-01 fctb = 1.180E+03
} 

#P SINGLET METHYLENE (S-CH2) REACTIONS

#PRef: frenklach:1992:pecs
55f: 	S-CH2 + OH -> CH2O + H	{ a = 3.000E+13 n = 0.000 E =   0.000 } 
56f: 	S-CH2 + O2 -> CO + OH + H	{ a = 3.130E+13 n = 0.000 E =   0.000 }
#PRef: leung:1995:candf
57f: 	S-CH2 + CO2 -> CO + CH2O	{ a = 3.000E+12 n = 0.000 E =   0.000 } 
#PRef: frenklach:1992:pecs
58f: 	S-CH2 + M10 -> T-CH2 + M10	{ a = 6.000E+12 n = 0.000 E =   0.000 }

#P TRIPLET METHYLENE (T-CH2) REACTIONS

#PRef: baulch:1992:physchem
59f: 	T-CH2 + H -> CH + H2	{ a = 6.020E+12 n = 0.000 E =  -7.480 } 
#PRef: frenklach:1992:pecs
60f: 	T-CH2 + OH -> CH2O + H	{ a = 2.500E+13 n = 0.000 E =   0.000 } 
61f: 	T-CH2 + OH -> CH + H2O	{ a = 1.130E+07 n = 2.000 E =  12.550 }
#PRef: frank:1986:21stsymp
62f: 	T-CH2 + O -> CO + 2H	{ a = 8.000E+13 n = 0.000 E =   0.000 } 
63f: 	T-CH2 + O -> CO + H2	{ a = 4.000E+13 n = 0.000 E =   0.000 }
#PRef: leung:1995:candf
64f: 	T-CH2 + O2 -> CO2 + H2	{ a = 2.630E+12 n = 0.000 E =   6.240 } 
65f: 	T-CH2 + O2 -> CO + OH + H	{ a = 6.580E+12 n = 0.000 E =   6.240 } 
#PRef: frenklach:1992:pecs
66f: 	T-CH2 + T-CH2 -> C2H2 + 2H	{ a = 1.000E+14 n = 0.000 E =   0.000 } 

#P  METHYNE (CH) REACTIONS
#PRef: peters:1993:redmech
67f: 	CH + O -> CO + H	{ a = 4.000E+13 n = 0.000 E =   0.000 } 
#PRef: markus:1996:intjchemkin
68f: 	CH + O2 -> HCO + O	{ a = 1.770E+11 n = 0.760 E =  -2.000 } 
#PRef: leung:1995:candf
69f: 	CH + H2O -> CH2O + H	{ a = 1.170E+15 n = -0.750 E =   0.000 } 
#PRef: markus:1996:intjchemkin
70f: 	CH + CO2 -> HCO + CO	{ a = 4.800E+01 n = 3.220 E = -13.500 } 

#P  METHOXY (CH3O) REACTIONS

#PRef: li:1998:27thsymp
71f: 	CH3O + H -> CH2O + H2	{ a = 2.000E+13 n = 0.000 E =   0.000 } 
72f: 	CH3O + H -> S-CH2 + H2O	{ a = 1.600E+13 n = 0.000 E =   0.000 } 
73f: 	CH3O + OH -> CH2O + H2O	{ a = 5.000E+12 n = 0.000 E =   0.000 } 
74f: 	CH3O + O -> OH + CH2O	{ a = 1.000E+13 n = 0.000 E =   0.000 } 
75f: 	CH3O + O2 -> CH2O + HO2	{ a = 4.280E-13 n = 7.600 E = -14.800 } 
#PRef: saxena:2007:thesis
76f: 	CH3O + M9 -> CH2O + H + M9	{ a = 7.780E+13 n = 0.000 E =  56.540 } 

#P  ETHANE (C2H6) REACTION

#PRef: frenklach:1992:pecs
77f: 	C2H6 + H -> C2H5 + H2	{ a = 5.400E+02 n = 3.500 E =  21.800 } 
78f: 	C2H6 + O -> C2H5 + OH	{ a = 1.400E+00 n = 4.300 E =  11.600 } 
79f: 	C2H6 + OH -> C2H5 + H2O	{ a = 2.200E+07 n = 1.900 E =   4.700 } 
80f: 	C2H6 + CH3 -> C2H5 + CH4	{ a = 5.500E-01 n = 4.000 E =  34.700 } 
#PRef: hewson:1999:methane, webpage:gri12, saxena:2007:thesis
81f: 	C2H6 + M8 -> C2H5 + H + M8	{ ai = 8.850E+20 ni = -1.230 Ei = 427.700 
			 a = 4.900E+42 n = -6.430 E = 448.399 
	fca = 1.600E-01 fcta = 1.250E+02 fcb = 8.400E-01 fctb = 2.219E+03 fcc = 1 fctc = 6.882E+03 
} 
#PRef: baulch:1992:physchem, saxena:2007:thesis
82f: 	C2H6 + HO2 -> C2H5 + H2O2	{ a = 1.320E+13 n = 0.000 E =  85.646 }

#P   ETHYL (C2H5) REACTIONS
#PRef: frenklach:1992:pecs
83f: 	C2H5 + H -> C2H4 + H2	{ a = 3.000E+13 n = 0.000 E =   0.000 } 
84f: 	C2H5 + O -> C2H4 + OH	{ a = 3.060E+13 n = 0.000 E =   0.000 } 
85f: 	C2H5 + O -> CH3 + CH2O	{ a = 4.240E+13 n = 0.000 E =   0.000 } 
#PRef:  Prince:2012
86f: 	C2H5 + O2 -> C2H4 + HO2	{ a = 7.500E+14 n = -1.000 E =  20.083} 
a86f:   C2H5 + O2 -> C2H4OOH    { a = 2.000e+12 n = 0.000  E =  0.000 }
b86f:   C2H4OOH  -> C2H4 + HO2  { a = 4.000e+34 n = -7.200 E =  96.232}
c86f:   C2H4OOH  + O2 -> OC2H3OOH + OH { a = 7.500e+05 n = 1.300 E = -24.267}
d86f:   OC2H3OOH -> CH2O + HCO + OH { a = 1.000e+15 n = 0.000 E = 179.912}
 
#PRef: feng:1993:c2h5, saxena:2007:thesis
87f: 	C2H5 + M9 -> C2H4 + H + M9	{ ai = 1.110E+10 ni = 1.037 Ei = 153.840 
			 a = 3.990E+33 n = -4.990 E = 167.360 
	fca = 8.320E-01 fcta = 1.203E+03 fcb = 1.680E-01 fctb = 1.000E-30
} 

#P   ETHENE (C2H4) REACTIONS
#PRef: bhargava:1998:candf
88f: 	C2H4 + H -> C2H3 + H2	 	{ a = 4.490E+07 n = 2.120 E =  55.900 } 
89f: 	C2H4 + OH -> C2H3 + H2O		{ a = 5.530E+05 n = 2.310 E =  12.400 } 
#PRef: baulch:1992:physchem
90f: 	C2H4 + O -> CH3 + HCO		{ a = 2.250E+06 n = 2.080 E =   0.000 } 
91f: 	C2H4 + O -> CH2CHO + H		{ a = 1.210E+06 n = 2.080 E =   0.000 } 
#PRef: hidaka:1999:ethylene
92f: 	C2H4 + C2H4 -> C2H3 + C2H5	{ a = 5.010E+14 n = 0.000 E = 270.705 } 
#PRef: marinov:1995:ethylene
93f: 	C2H4 + O2 -> C2H3 + HO2	{ a = 4.220E+13 n = 0.000 E = 241.095 } 
#PRef: baulch:1992:physchem
94f: 	C2H4 + HO2 -> C2H4O + OH	{ a = 2.230E+12 n = 0.000 E =  71.920 } 
95f: 	C2H4O + HO2 -> CH3 + CO + H2O2	{ a = 4.000E+12 n = 0.000 E =  71.160 }
#PRef: baulch:1994:candf, saxena:2007:thesis
96f: 	C2H4 + M9 -> C2H3 + H + M9	{ a = 2.600E+17 n = 0.000 E = 404.041 } 
97f: 	C2H4 + M9 -> C2H2 + H2 + M9	{ a = 3.500E+16 n = 0.000 E = 299.290 } 

#P   VINYL (C2H3) REACTIONS
#PRef: saxena:2007:thesis
98f: 	C2H3 + H -> C2H2 + H2	{ a = 4.000E+13 n = 0.000 E =   0.000 } 
#PRef: varatharajan:2001:acetylene, saxena:2007:thesis
99f: 	C2H3 + M9 -> C2H2 + H + M9	{ ai = 6.380E+09 ni = 1.000 Ei = 157.430 
			 a = 1.510E+14 n = 0.100 E = 136.758 
	fca = 7.000E-01 fcta = 1.000E+30 fcb = 3.000E-01 fctb = 1.000E-30
}
#PRef: marinov:1998:pitz
100f: C2H3 + O2 -> CH2O + HCO	{ a = 1.700E+29 n = -5.312 E =  27.209 } 
#PRef: varatharajan:2001:acetylene, marinov:1998:pitz
101f: C2H3 + O2 -> CH2CHO + O	{ a = 7.000E+14 n = -0.611 E =  22.018 } 
#PRef: varatharajan:2001:acetylene, marinov:1998:pitz
102f: C2H3 + O2 -> C2H2 + HO2	{ a = 5.190E+15 n = -1.260 E =  13.860 }

#P   ACETYLENE (C2H2) REACTIONS
#PRef: frank:1986:21stsymp
103f: C2H2 + O -> HCCO + H	{ a = 4.000E+14 n = 0.000 E =  44.600 } 
104f: C2H2 + O -> T-CH2 + CO	{ a = 1.600E+14 n = 0.000 E =  41.400 }
#PRef: laskin:1999:initiation
105f: C2H2 + O2 -> CH2O + CO	{ a = 4.600E+15 n = -0.540 E = 188.000 } 
#PRef: lindstedt:1997:acetylene, waly:2001:natgas
106f: C2H2 + OH -> CH2CO + H	{ a = 1.900E+07 n = 1.700 E =   4.180 } 
107f: C2H2 + OH -> C2H + H2O	{ a = 3.370E+07 n = 2.000 E =  58.580 } 

#P   CH2CO REACTIONS
#PRef: petrova:2005:williams
108f: CH2CO + H -> CH3 + CO	{ a = 1.500E+09 n = 1.430 E =  11.250 } 
#PRef: lindstedt:1997:acetylene, waly:2001:natgas
109f: CH2CO + O -> T-CH2 + CO2	{ a = 2.000E+13 n = 0.000 E =   9.600 } 
110f: CH2CO + O -> HCCO + OH	{ a = 1.000E+13 n = 0.000 E =   8.370 } 
111f: CH2CO + CH3 -> C2H5 + CO	{ a = 9.000E+10 n = 0.000 E =   0.000 } 

#P   HCCO REACTIONS
#PRef: frank:1986:21stsymp
112f: HCCO + H -> S-CH2 + CO	{ a = 1.500E+14 n = 0.000 E =   0.000 }
#PRef: westbrook:1984:pecs
113f: HCCO + OH -> HCO + CO + H	{ a = 2.000E+12 n = 0.000 E =   0.000 }
#PRef: frank:1986:21stsymp
114f: HCCO + O -> 2CO + H	{ a = 9.640E+13 n = 0.000 E =   0.000 }
#PRef: varatharajan:2001:acetylene
115f: HCCO + O2 -> 2CO + OH	{ a = 2.880E+07 n = 1.700 E =   4.190 } 
116f: HCCO + O2 -> CO2 + CO + H	{ a = 1.400E+07 n = 1.700 E =   4.190 }

#P   C2H FORMATION AND CONSUMPTION
#PRef: frenklach:1992:pecs, waly:2001:natgas
117f: C2H + OH -> HCCO + H	{ a = 2.000E+13 n = 0.000 E =   0.000 } 
118f: C2H + O -> CO + CH	{ a = 1.020E+13 n = 0.000 E =   0.000 } 
119f: C2H + O2 -> HCCO + O	{ a = 6.020E+11 n = 0.000 E =   0.000 } 
120f: C2H + O2 -> CH + CO2	{ a = 4.500E+15 n = 0.000 E = 105.000 } 
121f: C2H + O2 -> HCO + CO	{ a = 2.410E+12 n = 0.000 E =   0.000 }

#P   HYDROXYMETHYL (CH2OH)  REACTIONS
#PRef: li:1998:27thsymp
122f: CH2OH + H -> CH2O + H2	{ a = 3.000E+13 n = 0.000 E =   0.000 }
#PRef: saxena:2007:thesis
123f: CH2OH + H -> CH3 + OH	{ a = 2.500E+17 n = -0.930 E =  21.451 } 
#PRef: li:1998:27thsymp
124f: CH2OH + OH -> CH2O + H2O	{ a = 2.400E+13 n = 0.000 E =   0.000 } 
125f: CH2OH + O2 -> CH2O + HO2	{ a = 5.000E+12 n = 0.000 E =   0.000 } 
126f: CH2OH + M9 -> CH2O + H + M9	{ a = 5.000E+13 n = 0.000 E = 105.100 } 
127f: CH3O + M9 -> CH2OH + M9	{ a = 1.000E+14 n = 0.000 E =  80.000 } 
128f: CH2CO + OH -> CH2OH + CO	{ a = 1.020E+13 n = 0.000 E =   0.000 }

#P   METHANOL (CH3OH) REACTIONS
#PRef: li:1998:27thsymp
129f: CH3OH + OH -> CH2OH + H2O	{ a = 1.440E+06 n = 2.000 E =  -3.510 }
#PRef: saxena:2007:thesis
130f: CH3OH + OH -> CH3O + H2O	{ a = 4.400E+06 n = 2.000 E =   6.300 } 
#PRef: jodkowski:1999
131f: CH3OH + H -> CH2OH + H2		{ a = 1.354E+03 n = 3.200 E =  14.605 } 
132f: CH3OH + H -> CH3O + H2		{ a = 6.830E+01 n = 3.400 E =  30.292 } 
#PRef: driver:1992
133f: CH3OH + O -> CH2OH + OH	{ a = 3.880E+05 n = 2.500 E =  12.890 } 
#PRef: norton:1990:methanol, seiser:2011:methanol
134f: CH3OH + HO2 -> CH2OH + H2O2	{ a = 8.000E+13 n = 0.000 E =  81.100 } 
#PRef: li:1998:27thsymp
135f: CH3OH + O2 -> CH2OH + HO2	{ a = 2.000E+13 n = 0.000 E = 188.000 } 
#PRef: held:1998, saxena:2007:thesis
136f: CH3OH + M9 -> CH3 + OH + M9	{ ai = 1.900E+16 ni = 0.000 Ei = 383.798 
			 a = 2.950E+44 n = -7.350 E = 399.405 
	fca = 5.860E-01 fcta = 2.790E+02 fcb = 4.140E-01 fctb = 5.459E+03
} 

#P   CH2CHO REACTIONS
#PRef: marinov:1995:ethylene
137f: CH2CHO -> CH2CO + H		{ a = 1.047E+37 n = -7.189 E = 185.520 } 
#PRef: li:thesis
138f: CH2CHO + H -> CH3 + HCO		{ a = 5.000E+13 n = 0.000 E =   0.000 } 
139f: CH2CHO + H -> CH2CO + H2	{ a = 2.000E+13 n = 0.000 E =   0.000 } 
140f: CH2CHO + O -> CH2O + HCO	{ a = 1.000E+14 n = 0.000 E =   0.000 } 
141f: CH2CHO + OH -> CH2CO + H2O	{ a = 3.000E+13 n = 0.000 E =   0.000 } 
142f: CH2CHO + O2 -> CH2O + CO + OH	{ a = 3.000E+10 n = 0.000 E =   0.000 } 
143f: CH2CHO + CH3 -> C2H5 + CO + H	{ a = 4.900E+14 n = -0.500 E =   0.000 } 
144f: CH2CHO + HO2 -> CH2O + HCO + OH	{ a = 7.000E+12 n = 0.000 E =   0.000 } 
145f: CH2CHO + HO2 -> CH3CHO + O2	{ a = 3.000E+12 n = 0.000 E =   0.000 } 
146f: CH2CHO -> CH3 + CO		{ a = 1.170E+43 n = -9.800 E = 183.259 } 

#P   ACETALDEHYDE (CH3CHO) REACTIONS
#PRef: li:thesis
147f: CH3CHO -> CH3 + HCO	{ a = 7.000E+15 n = 0.000 E = 341.833 } 
148f: CH3CO + M9-> CH3 + CO + M9	{ ai = 3.000E+12 ni = 0.000 Ei =  69.873 
			 a = 1.200E+15 n = 0.000 E =  52.300 
	fcc = 1.0 fctc = 0.0
} 
149f: CH3CHO + OH -> CH3CO + H2O	{ a = 3.370E+12 n = 0.000 E =  -2.594 } 
150f: CH3CHO + OH -> CH2CHO + H2O	{ a = 3.370E+11 n = 0.000 E =  -2.594 } 
151f: CH3CHO + O -> CH3CO + OH	{ a = 1.770E+18 n = -1.900 E =  12.468 } 
152f: CH3CHO + O -> CH2CHO + OH	{ a = 3.720E+13 n = -0.200 E =  14.895 } 
153f: CH3CHO + H -> CH3CO + H2	{ a = 4.660E+13 n = -0.300 E =  12.510 } 
154f: CH3CHO + H -> CH2CHO + H2	{ a = 1.850E+12 n = 0.400 E =  22.426 } 
155f: CH3CHO + CH3 -> CH3CO + CH4	{ a = 3.900E-07 n = 5.800 E =   9.205 } 
156f: CH3CHO + CH3 -> CH2CHO + CH4	{ a = 2.450E+01 n = 3.100 E =  23.974 } 
157f: CH3CHO + HO2 -> CH3CO + H2O2	{ a = 3.600E+19 n = -2.200 E =  58.576 } 
158f: CH3CHO + HO2 -> CH2CHO + H2O2	{ a = 2.320E+11 n = 0.400 E =  62.342 } 
159f: CH3CHO + O2 -> CH3CO + HO2	{ a = 1.000E+14 n = 0.000 E = 176.565 } 

#P   ETHANOL (C2H5OH) REACTIONS

#PRef: saxena:2007:thesis, saxena:2007:ethanol
160f: C2H5OH + M9 -> CH3 + CH2OH + M9	{ ai = 5.000E+15 ni = 0.000 Ei = 343.088 
			 a = 3.000E+16 n = 0.000 E = 242.672 
	fca = 5.000E-01 fcta = 1.000E-30 fcb = 5.000E-01 fctb = 1.000E+30
} 
161f: C2H5OH + M9 -> C2H4 + H2O + M9	{ ai = 8.000E+13 ni = 0.000 Ei = 271.960 
			 a = 1.000E+17 n = 0.000 E = 225.936 
	fca = 5.000E-01 fcta = 1.000E-30 fcb = 5.000E-01 fctb = 1.000E+30
} 
#PRef: li:thesis, saxena:2007:ethanol
162f: C2H5OH + OH -> CH2CH2OH + H2O	{ a = 1.810E+11 n = 0.400 E =   3.000 } 
163f: C2H5OH + OH -> CH3CHOH + H2O	{ a = 3.090E+10 n = 0.500 E =  -1.590 } 
164f: C2H5OH + OH -> CH3CH2O + H2O	{ a = 1.050E+10 n = 0.800 E =   3.000 } 
165f: C2H5OH + H -> CH2CH2OH + H2	{ a = 1.900E+07 n = 1.800 E =  21.338 } 
166f: C2H5OH + H -> CH3CHOH + H2	{ a = 2.580E+07 n = 1.600 E =  11.841 } 
167f: C2H5OH + H -> CH3CH2O + H2	{ a = 1.500E+07 n = 1.600 E =  12.719 } 
168f: C2H5OH + O -> CH2CH2OH + OH	{ a = 9.410E+07 n = 1.700 E =  22.845 } 
169f: C2H5OH + O -> CH3CHOH + OH	{ a = 1.880E+07 n = 1.900 E =   7.615 } 
170f: C2H5OH + O -> CH3CH2O + OH	{ a = 1.580E+07 n = 2.000 E =  18.619 } 
171f: C2H5OH + CH3 -> CH2CH2OH + CH4	{ a = 2.190E+02 n = 3.200 E =  40.250 } 
172f: C2H5OH + CH3 -> CH3CHOH + CH4	{ a = 7.280E+02 n = 3.000 E =  33.263 } 
173f: C2H5OH + CH3 -> CH3CH2O + CH4	{ a = 1.450E+02 n = 3.000 E =  32.008 } 
174f: C2H5OH + HO2 -> CH3CHOH + H2O2	{ a = 8.200E+03 n = 2.500 E =  45.187 } 
175f: C2H5OH + HO2 -> CH2CH2OH + H2O2	{ a = 2.430E+04 n = 2.500 E =  66.107 } 
176f: C2H5OH + HO2 -> CH3CH2O + H2O2	{ a = 3.800E+12 n = 0.000 E = 100.416 } 

#P    C2H5O REACTIONS 
177f: C2H4 + OH -> CH2CH2OH	{ a = 2.410E+11 n = 0.000 E =  -9.958 } 
178f: C2H5 + HO2 -> CH3CH2O + OH	{ a = 4.000E+13 n = 0.000 E =   0.000 } 
179f: CH3CH2O + M9 -> CH3CHO + H + M9	{ a = 5.600E+34 n = -5.900 E = 105.855 } 
180f: CH3CH2O + M9 -> CH3 + CH2O + M9	{ a = 5.350E+37 n = -7.000 E =  99.579 } 
181f: CH3CH2O + O2 -> CH3CHO + HO2	{ a = 4.000E+10 n = 0.000 E =   4.602 } 
182f: CH3CH2O + CO -> C2H5 + CO2	{ a = 4.680E+02 n = 3.200 E =  22.510 } 
183f: CH3CH2O + H -> CH3 + CH2OH	{ a = 3.000E+13 n = 0.000 E =   0.000 } 
184f: CH3CH2O + H -> C2H4 + H2O	{ a = 3.000E+13 n = 0.000 E =   0.000 } 
185f: CH3CH2O + OH -> CH3CHO + H2O	{ a = 1.000E+13 n = 0.000 E =   0.000 } 
186f: CH3CHOH + O2 -> CH3CHO + HO2	{ a = 4.820E+13 n = 0.000 E =  21.004 } 
187f: CH3CHOH + O -> CH3CHO + OH	{ a = 1.000E+14 n = 0.000 E =   0.000 } 
188f: CH3CHOH + H -> C2H4 + H2O	{ a = 3.000E+13 n = 0.000 E =   0.000 } 
189f: CH3CHOH + H -> CH3 + CH2OH	{ a = 3.000E+13 n = 0.000 E =   0.000 } 
190f: CH3CHOH + HO2 -> CH3CHO + OH + OH	{ a = 4.000E+13 n = 0.000 E =   0.000 } 
191f: CH3CHOH + OH -> CH3CHO + H2O	{ a = 5.000E+12 n = 0.000 E =   0.000 } 
192f: CH3CHOH + M9 -> CH3CHO + H + M9	{ a = 1.000E+14 n = 0.000 E = 104.600 } 

#P   C3 REACTIONS
#PRef: davis:1999:propene
193f: C3H4 + O -> C2H4 + CO	{ a = 2.000E+07 n = 1.800 E =   4.184 } 
194f: CH3 + C2H2 -> C3H4 + H	{ a = 2.560E+09 n = 1.100 E =  57.086 } 
195f: C3H4 + O -> HCCO + CH3	{ a = 7.300E+12 n = 0.000 E =   9.414 } 
#PRef: petrova:2005:williams
196f: C3H3 + H + M -> C3H4 + M	{ ai = 3.000E+13 ni = 0.000 Ei =   0.000 
			 a = 9.000E+15 n = 1.000 E =   0.000 
	fca = 5.000E-01 fcta = 1.000E+30 fcb = 5.000E-01 fctb = 1.000E-30
} 
197f: C3H3 + HO2 -> C3H4 + O2	{ a = 2.500E+12 n = 0.000 E =   0.000 }

#P   ALLYL REACTIONS

#PRef: wang:1997:aromatics
198f: C3H4 + OH -> C3H3 + H2O	{ a = 5.300E+06 n = 2.000 E =   8.368 } 
#PRef: slagle:1986:symp
199f: C3H3 + O2 -> CH2CO + HCO	{ a = 3.000E+10 n = 0.000 E =  12.000 } 

#P    C3H5 REACTIONS 
#P  San Diego fit of Troe falloff for several values of pressure
#PRef: petrova:2005:williams
200f: C3H4 + H + M -> C3H5 + M	{ ai = 4.000E+13 ni = 0.000 Ei =   0.000 
			 a = 3.000E+24 n = -2.000 E =   0.000 

	fca = 2.000E-01 fcta = 1.000E+30 fcb = 8.000E-01 fctb = 1.000E-30
} 
#PRef: tsang:1991:physchem
201f: C3H5 + H -> C3H4 + H2	{ a = 1.800E+13 n = 0.000 E =   0.000 } 
#PRef: bozelli:1993:dean
202f: C3H5 + O2 -> C3H4 + HO2	{ a = 4.990E+15 n = -1.400 E =  93.839 } 
#PRef: petrova:2005:williams
203f: C3H5 + CH3 -> C3H4 + CH4	{ a = 3.000E+12 n = -0.320 E =  -0.548 } 
#P   San Diego fit of Troe falloff for several values of pressure
204f: C2H2 + CH3 + M -> C3H5 + M	{ ai = 6.000E+08 ni = 0.000 Ei =   0.000 
			 a = 2.000E+09 n = 1.000 E =   0.000 

	fca = 5.000E-01 fcta = 1.000E+30 fcb = 5.000E-01 fctb = 1.000E-30
} 
205f: C3H5 + OH -> C3H4 + H2O	{ a = 6.000E+12 n = 0.000 E =   0.000 } 
#P  Reactions added in DE, after C3H4 thermodata was changed to davis's aC3H4
#PRef: wang:1997:aromatics
206f: C3H3 + HCO -> C3H4 + CO	{ a = 2.500E+13 n = 0.000 E =   0.000 } 
#PRef: davis:1999:propene
207f: C3H3 + HO2 -> OH + CO + C2H3	{ a = 8.000E+11 n = 0.000 E =   0.000 } 
#PRef: wang:2001
208f: C3H4 + O2 -> CH3 + HCO + CO	{ a = 4.000E+14 n = 0.000 E = 175.000 } 

#P   PROPENE (C3H6) REACTIONS
#PRef: tsang:1991:physchem
209f: C3H6 + O -> C2H5 + HCO	{ a = 3.500E+07 n = 1.650 E =  -4.070 } 
210f: C3H6 + OH -> C3H5 + H2O	{ a = 3.100E+06 n = 2.000 E =  -1.248 } 
211f: C3H6 + O -> CH2CO + CH3 + H	{ a = 1.200E+08 n = 1.650 E =   1.370 } 
212f: C3H6 + H -> C3H5 + H2	{ a = 1.700E+05 n = 2.500 E =  10.430 } 
#PRef: davis:1999:propene
213f: C3H5 + H + M8 -> C3H6 + M8	{ ai = 2.000E+14 ni = 0.000 Ei =   0.000 
			 a = 1.330E+60 n = -12.000 E =  24.970 

	fca = 9.800E-01 fcta = 1.097E+03 fcb = 2.000E-02 fctb = 1.097E+03 fcc = 1 fctc = 6.860E+03 
} 
#PRef: baulch:1992:physchem
214f: C3H5 + HO2 -> C3H6 + O2	{ a = 2.660E+12 n = 0.000 E =   0.000 } 
#P   the rate from Baulch has been modified in San Diego Mechanism
215f: C3H5 + HO2 -> OH + C2H3 + CH2O	{ a = 3.000E+12 n = 0.000 E =   0.000 } 
#PRef: davis:1999:propene
216f: C2H3 + CH3 + M8 -> C3H6 + M8	{ ai = 2.500E+13 ni = 0.000 Ei =   0.000 
			 a = 4.270E+58 n = -11.940 E =  40.880 

	fca = 8.250E-01 fcta = 1.341E+03 fcb = 1.750E-01 fctb = 6.000E+04 fcc = 1 fctc = 1.014E+04 
} 
217f: C3H6 + H -> C2H4 + CH3	{ a = 1.600E+22 n = -2.390 E =  46.800 } 
218f: CH3 + C2H3 -> C3H5 + H	{ a = 1.500E+24 n = -2.830 E =  77.900 } 

#P   PROPANE (C3H8) REACTIONS

#PRef: baulch:1994:candf
219f: C3H8 + M -> CH3 + C2H5 + M	{ ai = 1.100E+17 ni = 0.000 Ei = 353.100 
			 a = 7.830E+18 n = 0.000 E = 271.868 

	fca = 2.400E-01 fcta = 1.946E+03 fcb = 7.600E-01 fctb = 3.800E+01
} 
#PRef: varatharajan:2000:bcte, davis:1999:propene, tsang:1988:physchem
220f: C3H8 + O2 -> I-C3H7 + HO2	{ a = 4.000E+13 n = 0.000 E = 198.740 } 
221f: C3H8 + O2 -> N-C3H7 + HO2	{ a = 4.000E+13 n = 0.000 E = 213.100 } 
222f: C3H8 + H -> I-C3H7 + H2	{ a = 1.300E+06 n = 2.400 E =  18.707 } 
#PRef: tsang:1988:physchem, marinov:1996:aromatic
223f: C3H8 + H -> N-C3H7 + H2	{ a = 1.330E+06 n = 2.540 E =  28.290 } 
#PRef: tsang:1988:physchem, davis:1999:propene
224f: C3H8 + O -> I-C3H7 + OH	{ a = 4.760E+04 n = 2.710 E =   8.817 } 
225f: C3H8 + O -> N-C3H7 + OH	{ a = 1.900E+05 n = 2.680 E =  15.558 } 
#PRef: Prince:2012
226f: C3H8 + OH -> N-C3H7 + H2O	{ a = 1.000e+10 n = 1.000 E =   6.694 } 
227f: C3H8 + OH -> I-C3H7 + H2O	{ a = 2.000e+07  n = -1.600 E =   -0.418 }
#PRef: tsang:1988:physchem, marinov:1996:aromatic, davis:1999:propene
228f: C3H8 + HO2 -> I-C3H7 + H2O2	{ a = 9.640E+03 n = 2.600 E =  58.230 } 
229f: C3H8 + HO2 -> N-C3H7 + H2O2	{ a = 4.760E+04 n = 2.550 E =  69.000 } 

#P   I-C3H7 REACTIONS

#PRef: tsang:1988:physchem, qin:1998:thesis
230f: I-C3H7 + C3H8 -> N-C3H7 + C3H8	{ a = 8.400E-03 n = 4.200 E =  36.300 } 
#PRef: davis:1999:propene
231f: C3H6 + H + M8 -> I-C3H7 + M8	{ ai = 1.330E+13 ni = 0.000 Ei =   6.530 
			 a = 8.700E+42 n = -7.500 E =  19.800 
	fca = 0.000E+00 fcta = 1.000E+03 fcb = 1.000E+00 fctb = 6.454E+02 fcc = 1 fctc = 6.844E+03 
} 
#PRef: tsang:1988:physchem, davis:1999:propene
232f: I-C3H7 + O2 -> C3H6 + HO2	{ a = 1.300E+11 n = 0.000 E =   0.000 } 
233f: N-C3H7 + M -> CH3 + C2H4 + M	{ ai = 1.230E+13 ni = -0.100 Ei = 126.400 
			 a = 5.490E+49 n = -10.000 E = 149.699 

	fca = 2.170E+00 fcta = 2.510E+02 fcb = -1.170E+00 fctb = 1.000E-15 fcc = 1 fctc = 1.185E+03 
} 
#PRef: davis:1999:propene
#P    REVERSE
234f: H + C3H6 + M8 -> N-C3H7 + M8	{ ai = 1.330E+13 ni = 0.000 Ei =  13.640 
			 a = 6.260E+38 n = -6.660 E =  29.290 

	fca = 0.000E+00 fcta = 1.000E+03 fcb = 1.000E+00 fctb = 1.310E+03 fcc = 1 fctc = 4.810E+04 
} 
#PRef: Prince:2012
235f: N-C3H7 + O2 -> C3H6 + HO2	{ a = 3.500e+16 n = -1.60 E = 14.644 } 
a235f: N-C3H7 + O2 -> C3H6OOH { a = 2.000e+12  n = 0.000 E = 0.000 }
b235f: C3H6OOH  -> C3H6 + HO2 { a = 2.500e+35 n = -8.300 E = 92.048 }
c235f: C3H6OOH  + O2 -> OC3H5OOH + OH { a = 1.500e+08  n = 0.000  E = -29.288 }
d235f: OC3H5OOH  -> CH2CHO + CH2O + OH { a = 1.000e+15 n = 0.000  E = 179.912
}


let M = 1.0[OTHER].
let M1 = 2.50 [H2] + 12.00 [H2O] + 1.90 [CO] + 3.80 [CO2] + 0.50 [AR] + 0.50 [HE] + 1.0 [OTHER]. 
let M2 = 2.50 [H2] + 12.00 [H2O] + 1.90 [CO] + 3.80 [CO2] + 0.38 [AR] + 0.38 [HE] + 1.0 [OTHER]. 
let M3 = 2.50 [H2] + 12.00 [H2O] + 1.90 [CO] + 3.80 [CO2] + 0.20 [AR] + 0.20 [HE] + 1.0 [OTHER]. 
let M4 = 2.50 [H2] + 12.00 [H2O] + 0.75 [AR] + 0.75 [HE] + 1.90 [CO] + 3.80 [CO2] + 1.0 [OTHER]. 
let M5 = 0.70 [AR] + 0.70 [HE] + 1.00 [O2] + 16.00 [H2O] + 2.50 [H2] + 1.20 [CO] + 2.40 [CO2] + 1.50 [C2H6] + 1.0 [OTHER]. 
let M6 = 0.70 [AR] + 0.40 [HE] + 2.50 [H2] + 6.00 [H2O] + 6.00 [H2O2] + 1.50 [CO] + 2.00 [CO2]  + 1.0 [OTHER]. 
let M7 = 1.90 [H2] + 12.00 [H2O] + 2.50 [CO] + 2.50 [CO2] + 1.0 [OTHER]. 
let M8 = 2.00 [H2] + 6.00 [H2O] + 2.00 [CH4] + 1.50 [CO] + 2.00 [CO2] + 3.00 [C2H6] + 0.70 [AR] + 1.0 [OTHER]. 
let M9 = 2.00 [H2] + 6.00 [H2O] + 2.00 [CH4] + 1.50 [CO] + 2.00 [CO2] + 0.70 [AR] + 1.0 [OTHER]. 
let M10 = 2.40 [H2] + 15.40 [H2O] + 1.80 [CO] + 3.60 [CO2] + 1.0 [OTHER]. 
let M11 = 2.50 [H2] + 12.00 [H2O] + 2.00 [CO] + 4.00 [CO2] + 0.70 [AR] + 0.70 [HE] + 1.0 [OTHER].